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Vaporization of Nonvolatile and Matrix-Isolated Molecules Using a Novel Laser Vaporization Technique

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Abstract:

A technique is described which uses a laser-generated high-velocity polymer flyer to vaporize nonvolatile molecules and low-temperature matrix-isolated species. Morphology studies, time-of-flight measurements, static collection methods, and real-time laser-induced fluorescence were used to characterize the new vaporization technique. Cr(CO)6 in a mineral oil glass at 77 K, rhodamine dye, and naphthalene were vaporized in these experiments.

Keywords: Ablation; Laser; Laser-induced fluorescence (LIF); Polymer; Reactive intermediate; Time-of-flight (TOF) mass spectrometry; Vaporization

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702963906799

Affiliations: Department of Chemistry, University of Idaho, Moscow, Idaho 83843

Publication date: January 1, 1996

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