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How to Minimize Certain Artifacts in Fourier Self-Deconvolution

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Computers are common tools in spectroscopy and they offer new possibilities for extracting useful information from experimental data. One of these tools is resolution enhancement of infrared spectra with Fourier self-deconvolution. This procedure is often used for the analysis of the amide I band in proteins. It is part of most commercial spectroscopic software packages, especially in the FT-IR software in which Fourier transformation is the basis of the experimental procedure. Thus Fourier self-deconvolution is becoming a powerful tool in spectroscopy. Since the number of users is expected to increase rapidly, a warning against the problems and pitfalls of the technique is appropriate. Usually one starts the software with a certain set of deconvolution parameters and varies them by a visual check of the result. The resolution enhancement is increased until the spectrum looks unrealistic. Two kinds of artifacts can occur during the process: over-deconvolution, which results in the appearance of side lobes, and the uncontrolled increase of the noise.

Keywords: Fourier transform; Power spectrum; Resolution enhancement; Self-deconvolution

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/0003702953965533

Affiliations: 1: Institute of Biophysics, Semmelweis University of Medicine, Budapest, POB 263, H-1444 Hungary 2: Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200 D, B-3001 Leuven, Belgium

Publication date: October 1, 1995

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