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FT-IR Analysis of the Laser-Induced Dissociation of Methylphosphonic Difluoride

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Abstract:

The output of a continuous-wave carbon dioxide laser was used successfully for the dissociation of methylphosphonic difluoride. End product analysis using Fourier transform infrared spectroscopy revealed that the phosphorus-to-carbon bond was cleaved, yielding the products methane, ethene, ethyne, hydrophosphoryl difluoride, and a mixture of phosphorus compounds. These results are presented and discussed. The dissociation was optimized. A reaction mechanism of the dissociation is suggested.

Keywords: Infrared; Laser; Methylphosphonic difluoride

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702953964219

Affiliations: Weapons Sciences Directorate, AMSMI-RD-WS-CM, Research, Development, and Engineering Center, U. S. Army Missile Command, Redstone Arsenal, Alabama 35898-5248

Publication date: April 1, 1995

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