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Presence of Two Molecular Dynamic Processes in a Narrow Temperature Range: Cis-Trans Isomerization across Nineteen Chemical Bonds and Rotation about the CN Bond

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Abstract:

We report the basis for the presence of two molecular dynamic processes, in enamino spiro-ketal-type compounds (structure in Fig. 1), that occur in a 330-350 K temperature range. Nuclear magnetic resonance (NMR) is a powerful tool for investigating such molecular dynamic processes in small and large molecules. This capability is a result of the pronounced influence of dynamic effects on NMR spectra. Analysis of experimental NMR data suggests that one of the two molecular processes is cis-trans isomerization across nineteen chemical bonds. To the best of our knowledge, this is the first example of monitoring cis-trans isomerization involving this many chemical bonds by NMR.

Keywords: Cis-trans isomerization across 19 chemical bonds; Dynamic NMR; Molecular dynamic processes; Rotation about CN bond; Two coalescence temperatures

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/0003702953963355

Affiliations: 1: Center for Advanced Materials, Department of Chemistry, University of Massachusetts-Lowell, Lowell, Massachusetts 01854 2: The BOC Group, Technical Center, Murray Hill, New Jersey 07974

Publication date: January 1, 1995

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