@article {Judge:1994:0003-7028:1102, author = "Judge, John W. and McGuffin, Victoria L.", title = "Comparative Study of Photovoltaic and Photoconductive Detection Methods for Liquid-Phase Photoionization", journal = "Applied Spectroscopy", volume = "48", number = "9", year = "1994", abstract = "The photovoltaic method for the detection of liquid-phase photoionization in the absence of an applied electric field is compared to the traditional photoconductive method. Each system is characterized by means of signal and signal-to-noise ratio measurements with respect to laser pulse energy, applied voltage, electrode separation distance, solute concentration, and solvent composition. Although both techniques exhibit similar detection limits (1 × 10-7 M) for solutes in polar solvents such as methanol and water, the photovoltaic technique has a more extensive linear dynamic range (103). Moreover, this technique allows detection of solutes in ionic solutions with comparable detectability and linearity.", pages = "1102-1110", url = "http://www.ingentaconnect.com/content/sas/sas/1994/00000048/00000009/art00006", doi = "doi:10.1366/0003702944029587", keyword = "Photoionization, Photoconductive detection, Photovoltaic detection, Spectroscopic techniques, Instrumentation" }