New Fiber-Optic-Based High-Pressure Cell for Fluorescence Measurements in Near- and Supercritical Solvents

Authors: Rice, Jeanette K.; Dunbar, Richard A.; Bright, Frank V.

Source: Applied Spectroscopy, Volume 48, Issue 8, Pages 915-1032 (August 1994) , pp. 1030-1032(3)

Publisher: Society for Applied Spectroscopy

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Abstract:

Studies of fluorescent molecules in supercritical fluids have done much to improve our understanding of solute-fluid, as well as solute-solute, interactions. However, most of the current high-pressure optical cells used in this field are cumbersome to work with and difficult or tedious to clean. Our group previously reported on a fiber-optic interface based on a bifurcated fiber probe which allowed spectroscopic measurements in supercritical solvents.

Keywords: Fiber optic; Static fluorescence spectroscopy, Supercritical fluids

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/0003702944029758

Affiliations: Department of Chemistry, Acheson Hall, State University of New York at Buffalo, Buffalo, New York 14214

Publication date: August 1, 1994

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