Conformer Analysis Study of 1,2-Diiodotetrafluoroethane by Gas Chromatography/Fourier Transform Infrared Spectroscopy

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Abstract:

In this paper, the measurement of the energy difference between the rotational conformers of 1-2-diiodotetrafluoroethane by GC/FT-IR spectroscopy is demonstrated for the first time. The ΔH° obtained is lower than the value reported from the use of the neat vapor-phase method. The difference between the values may be attributed to solvent and adsorption effects.

Keywords: GC/FT-IR

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702944028533

Affiliations: 1: University of Dayton Research Institute, 300 College Park Avenue, Dayton, Ohio 45469 2: Department of Chemistry, Wright State University, Dayton, Ohio 45435 3: Southwestern Ohio Council of Higher Education, Dayton, Ohio 45420

Publication date: February 1, 1994

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