Theoretical Studies in EDXRF on a New Linear Relation: ln(Fluorescent Intensity Ratio of Analyte to Pure Analyte/Concentration of Analyte) Versus ln(Fluorescent Energy)

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The inaccuracies and validity of the approximate linear relation between ln(fluorescent intensity/concentration) and ln(fluorescent energy) are presented and discussed. We then present the derivation of a new linear relation between ln(fluorescent intensity ratio of analyte to pure analyte/ concentration of analyte) and ln(fluorescent energy) which is valid for all elements that can be excited by radiation sources, whether by tube x-ray or by radioisotope sources.

Keywords: X-ray fluorescence

Document Type: Research Article


Affiliations: Department of Physics, National University of Singapore, Singapore 0511

Publication date: December 1, 1993

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