Analyte Matrix Excitation Investigations in the High-Voltage Spark Discharge Using an Echelle/CCD System

$29.00 plus tax (Refund Policy)

Buy Article:

Abstract:

The matrix dependence of analyte excitation in the high-voltage spark discharge has been investigated. The analyte excitation distributions of Fe(I), Mo(I), and Cu(I) have been measured. The large wavelength range of a custom echelle/CCD system was exploited for these determinations. The analyte excitation within the high-voltage spark on a time-integrated basis was determined to be independent of both sample matrix and sampled species.

Keywords: Boltzmann plot; CCD; Echelle spectrometer; Emission spectrochemical analysis; Spark, ac

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702934066451

Affiliations: 1: School of Chemical Sciences, University of Illinois, Urbana-Champaign, Box 48, Roger Adams Laboratory, 600 S. Mathews St., Urbana, Illinois 61801; current address: Department of Chemistry, Indiana University, Bloomington, IN 47405 2: School of Chemical Sciences, University of Illinois, Urbana-Champaign, Box 48, Roger Adams Laboratory, 600 S. Mathews St., Urbana, Illinois 61801

Publication date: December 1, 1993

More about this publication?
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more