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Characterization and Application of an Infrared Linear Array Spectrometer for Time-Resolved Infrared Spectroscopy

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Abstract:

An infrared spectrometer is described which uses a 32-element InSb linear array detector. The infrared linear array (IRLA) spectrometer collects infrared spectra with a spectral width of 0.50 μm every 16 μs. The performance of the IRLA spectrometer is characterized with respect to signal-to-noise ratio, spectral resolution, time resolution, and instrumental line shape. The IRLA spectrometer is used to collect the time-resolved infrared spectra following 193-nm irradiation of a solution of Mo(CO)6 in hexane.

Keywords: Infrared; Linear array; Time-resolved spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702934334769

Affiliations: Department of Chemistry, Clippinger Laboratories, Ohio University, Athens, Ohio 45701

Publication date: October 1, 1993

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