Spinning-Cell FT-Raman Spectroscopy: Application to Crystalline Octacarbonyldicobalt(0), Co2(CO)8

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Abstract:

The complete Raman spectrum of crystalline octacarbonyldicobalt(0), Co2(CO)8, has been successfully obtained for the first time by using a Fourier transform instrument together with a spinning sample cell to avoid decomposition of Co2(CO)8 upon exposure to the near-IR laser radiation used to excite the spectrum. Previously, only limited regions of the Raman spectrum could be obtained with visible laser excitation because of extensive sample burning. The new FT-Raman results, combined with the related IR data from the literature, provide a better description of the vibrational properties of this important binary metal carbonyl complex.

Keywords: Co2(CO)8; FT-Raman; Octacarbonyldicobalt(0); Spinning cell

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702934068035

Affiliations: 1: Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec, H3A 2K6 Canada 2: Department of Mining and Metallurgy, McGill University, 3450 University Street, Montreal, Quebec, H3A 2A7 Canada

Publication date: August 1, 1993

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