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Gel Permeation Chromatography/Fourier Transform Infrared Interface for Polymer Analysis

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Abstract:

A new solvent elimination interface capable of operating at elevated temperatures, here 145°C, has been used to collect polymer molecular weight fractions eluting from a gel permeation chromatogram and to prepare them for IR analysis. The sample is deposited continuously onto a rotating germanium disk which can subsequently be scanned with the use of GC/FT-IR software, allowing direct access to the polymer or copolymer composition as a function of molecular weight. Data are presented here for an ethylene-propylene copolymer which has a distinct bimodal molecular weight distribution. Both the concentration profile and the "composition distribution" are examined. For the polymer concentration profile, comparison is made between the chromatogram obtained with a differential refractive index (DRI) detector and the IR detector (plotting the absorbance as a function of time using Gram-Schmidt vector orthogonalization). The copolymer composition is determined from the relative absorbance of methyl and methylene groups in the CH stretching region. The results show a small change in propylene content as a function of molecular weight, and there is good agreement between composition calculated with the use of the Gram-Schmidt and point-to-point methods.

Keywords: Analytical methods; GP/FT-IR

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702934067982

Affiliations: 1: Polymer Group, Exxon Chemical Company, 1900 East Linden Avenue, Linden, New Jersey 07036 2: Lab Connections, Inc., 5 Mount Royal Avenue, Marlborough, Massachusetts 01752

Publication date: August 1, 1993

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