FT-IR/ATR Study of Lithium Intercalation into Molybdenum Oxide Thin Film

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Abstract:

Molybdenum oxide thin films are deposited by thermal evaporation and sputtering, and lithium is inserted by a dry lithiation method. The FT-IR/ATR technique is used to study the formation and evolution of lithium bronze and lithium molybdate species. The mechanism of lithium intercalation is found to be dependent on the method of film preparation. The involvement of water molecules in the kinetics of lithiation is stressed.

Keywords: FT-IR/ATR spectroscopy; Intercalation; Molybdenum oxide; Thin films

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702934066866

Affiliations: 1: Department of Physics, Université de Moncton, Moncton, N.B., E1A 3E9 Canada 2: Department of Physics, Université de Moncton, Moncton, N.B., ElA 3E9 Canada

Publication date: June 1, 1993

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