@article {Abdillahi:1993:0003-7028:366, author = "Abdillahi, M.M.", title = "Analytical Feasibility of Graphite Rod VaporizationHelium Microwave-Induced Plasma (GRV/He-MIP) for Some Nonmetal Determinations", journal = "Applied Spectroscopy", volume = "47", number = "3", year = "1993", abstract = "Trace level quantities of some nonmetallic elements are determined by coupling graphite rod electrothermal vaporization with a helium microwave-induced plasma. Microliter liquid samples of chlorides, bromides, iodides, sulfides, and ammonium nitrogen have been introduced into a grooved graphite rod, where they were dried, ashed, and vaporized into the plasma. The analytical performance of the GRV/He-MIP was found to be an excellent excitation source for dry analyte vapors. The graphite rod vaporization device is well suited for sample introduction for a low-power microwave-induced plasma. Analytical calibration curves were obtained that have linearities between 2.5 to 5 orders of magnitude. Detection limits of the technique for 10-μL aqueous sample solutions are reported in the lower nanogram region. The common anions and cations did not show significant interference effects on the determination of traces of these nonmetals.", pages = "366-374", url = "http://www.ingentaconnect.com/content/sas/sas/1993/00000047/00000003/art00020", doi = "doi:10.1366/0003702934066802", keyword = "Emission spectroscopy, Instrumentation, ETV-MIP, Analytical methods, Spectroscopic techniques" }