Infrared Photoacoustic Spectra of the Solid Manganese(I) Carbonyl Halides, Mn(CO)5 X and [Mn(CO)4 X]2 (X = Cl, Br, I)

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Abstract:

Mid- and near-IR photoacoustic (PA) spectra have been measured at room temperature for two series of crystalline manganese(I) carbonyl halides: Mn(CO)5 X and [Mn(CO)4 X]2 (X = Cl, Br, I). Vibrational assignments are proposed for many of the observed bands. The PA spectra in the near-IR region (4200-3800 cm−1), where the binvary v(CO) overtones and combinations absorb, are useful spectral fingerprints for these organomanganese(I) complexes.

Keywords: Infrared; Photoacoustic spectra

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702924123557

Affiliations: Department of Chemistry, McGill University, 801 Sherbrooke St. West, Montreal, Quebec H3A 2K6, Canada

Publication date: December 1, 1992

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