Dynamic Background Correction by Wavelength Modulation in ICP Atomic Emission Spectrometry (AES) and its Application to Flow-Injection-ICP-AES
Abstract:This paper describes a fast background correction system based on wavelength modulation that can be adapted to any dispersive ICP spectrometer. It consists of a quartz refractor plate which oscillates just behind the entrance slit to perform rapid wavelength scanning across the emission line. The system inertia is small and allows a fast scan rate, which permits real-time background measurement during fast transient signals. It has been successfully applied to flow-injection-ICP-atomic emission analysis (FIA-ICP-AES). A simple and inexpensive interface is presented to perform wavelength modulation control and data acquisition by an IBM-XT microcomputer. Different mathematical approaches are compared to handle the spectral line intensity, as well as the FIA-AES peaks. The result is a simplified and fast data treatment which can be easily handled by any small microcomputer.
Document Type: Research Article
Affiliations: Department of Chemistry, Université de Montréal, P.O. Box 6128, Station A, Montréal, Québec H3C 3J7, Canada
Publication date: May 1, 1992
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