The Use of Singular Value Variance-Decomposition Proportions in FT-IR Analysis of Gases and Vapors

Author: Batterman, Stuart

Source: Applied Spectroscopy, Volume 46, Issue 5, Pages 715-882 (May 1992) , pp. 800-806(7)

Publisher: Society for Applied Spectroscopy

Buy & download fulltext article:

OR

Price: $29.00 plus tax (Refund Policy)

Abstract:

Issues in the application of spectral least-squares methods to Fourier transform infrared spectrophotometry are discussed with emphasis on collinearity problems in vapor and gas reference spectra. Excessive collinearity may degrade the accuracy and reliability of prediction. Several methods that detect and diagnose collinearity are developed and tested with the use of numerical experiments. The condition number is based on the singular values in the reference spectra matrix and provides a stable and composite measure of collinearity. Variance-decomposition proportions and auxiliary regressions identify the spectra that form dependencies. Application of the methods to spectra of common vapors and gases shows complex and potentially degrading dependencies that would not be seen by examining correlation coefficients or other statistics measuring only pair-wise dependencies. A method to estimate the precision of results for specified signal-to-noise ratios and degree of collinearity is evaluated.

Keywords: Collinearity; Fourier transform infrared spectrometry; Least-squares methods; Trace gas analysis

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702924124745

Affiliations: School of Public Health, University of Michigan, Ann Arbor, Michigan 48109-2029

Publication date: May 1, 1992

More about this publication?
Related content

Tools

Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content

Text size:

A | A | A | A
Share this item with others: These icons link to social bookmarking sites where readers can share and discover new web pages. print icon Print this page