Selective Determination of Pentafluorobenzyl Ester Derivatives of Carboxylic Acids by GC Using Microwave Plasma and Mass Selective Detection

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Abstract:

A highly selective, sensitive method for determination of carboxylic acids in water has been developed that is based on fluorine-selective gas chromatography (GC) detection of pentafluorobenzyl ester derivatives. The atmospheric-pressure helium microwave-induced plasma detector is well suited for fluorine-specific detection of these derivatives, which were well resolved by capillary GC and displayed a characteristic fragmentation behavior when examined by GC-mass selective detection. For demonstration purposes, a number of carboxylic acids, ranging from C1 to C20, were examined and found to be derivatized with yields greater than 90%, and a sample of creek water was examined for its carboxylic acid content.

Keywords: Carboxylic acids; Fluorine; Microwave-induced plasma detector; Pentafluorobenzyl esters

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702914335193

Affiliations: Department of Chemistry, University of Missouri, Columbia, Missouri 65211

Publication date: December 1, 1991

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