Infrared Study of Dimethylacetamide in Chloroform and/or Carbon Tetrachloride 1% Solutions

Authors: Nyquist, Richard A.; Luoma, Davin A.

Source: Applied Spectroscopy, Volume 45, Issue 9, Pages 1391-1570 (November 1991) , pp. 1501-1503(3)

Publisher: Society for Applied Spectroscopy

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In carbon tetrachloride and/or chloroform solutions, the behavior of the carbonyl stretching mode, νC=O, versus mole % CHCl3/CCl4 can be explained on the basis of the bulk dielectric effect of the solvent system and the existence of hydrogen-bonded complexes between solute and solvent and between solvent molecules.

Keywords: C=O stretching; Group frequencies; Infrared; Molecular structure; Solvent effects

Document Type: Research Article


Affiliations: The Dow Chemical Company, Analytical Sciences Laboratory, 1897 Building, Midland, Michigan 48667

Publication date: November 1, 1991

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