Design and Properties of New IR Liquid Cells with Free Access to the Reaction Volume: Application to Temperature-Dependent Studies of the (Photo)reactions of Some Transition Metal Carbonyls

$29.00 plus tax (Refund Policy)

Buy Article:

Abstract:

This article describes the construction and properties of new infrared cells for low- and room–temperature studies of (photo)chemical reactions. Both cells consist of three components—viz., a reaction vessel, an IR measurement cell, and a suction unit—which are interconnected by tubes, thus forming a closed system. The main advantages of the cells are that gaseous products of (photo) reactions can be removed and reagents can be added at a later stage of the reaction or at low temperature. The free access to the reaction vessel also facilitates sampling from the IR solution for analytical purposes. These great advantages are demonstrated by a few representative (photo) reactions of transition metal carbonyls.

Keywords: Infrared; Inorganic chemistry; Metathesis; Organometallic photochemistry; Transition metal carbonyls

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702914335742

Affiliations: Anorganisch Chemisch Laboratorium, Universiteit van Amsterdam, J.H. van't Hoff Instituut, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands

Publication date: September 1, 1991

More about this publication?
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more