Accurate OH Bond Angle Determination in Trigonal Crystals

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Abstract:

Polarized optical absorption spectroscopy is a standard technique used for determining the bond angle of an OH dipole aligned at an angle, , to the threefold c-axis of a trigonal crystal. Optical absorption spectra are measured with the electric vector, E, of the incident light both perpendicular and parallel to the trigonal symmetry axis. The dipole bond angle is usually calculated with the use of the following expression:

(α⊥c)/(α∥c) = (1.5 sin2)/(3 cos2) = (1/2) tan2

where  is the OH dipole bond angle to the c-axis, and α⊥c and α∥c are the absorption coefficients of the measured IR bands with Ec and Ec, respectively.

Keywords: Bond angle; IR spectroscopy; OH bonds; Sapphire

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702914336318

Affiliations: Department of Applied Physics, University of Technology, Sydney, P.O. Box 123, Sydney, Australia 2007

Publication date: July 1, 1991

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