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Vibrational Spectroscopic Evidence for the Associated-Anion Promotion of the Helical Structure of N-Acylglycine Oligomers

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Abstract:

Vibrational spectroscopic evidence for conformational change of the anions of N-acylglycine oligomers (trimers, tetramers, and pentamers) in aqueous solution is reported. The infrared absorption spectra of sample solutions diluted below the critical micelle concentration (cmc) can be explained by the coexistence of several conformations containing the polyglycine I-like extended form and the polyglycine II-like helix. However, above the cmc the infrared bands arising from the polyglycine II-like helix are intensified. This result is due to preferential stabilization of the helical structure, promoted by intermolecular association of the anions. The helical structure is also stable in the hydrophobic environment of micelles.

Keywords: Fourier transform infrared spectra; Helical structure; Micelle; N-Acylglycine oligomer; Raman spectra

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702914336822

Affiliations: 1: Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466, Japan 2: Osaka Laboratory, Perkin-Elmer Japan, Toyotsu, Suita 564, Japan

Publication date: May 1, 1991

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sas/sas/1991/00000045/00000004/art00018
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