@article {Nyquist:1990:0003-7028:791, author = "Nyquist, Richard A. and Settineri, Sam E.", title = "Infrared Study of Coumarin in Different Solvent Systems", journal = "Applied Spectroscopy", volume = "44", number = "5", year = "1990", abstract = "Coumarin exhibits two infrared bands in the carbonyl stretching region of the spectrum. The doublet is due to Fermi resonance (F.R.) of the carbonyl stretching mode, vC=O, with an overtone of a lower-lying fundamental. The vC=O mode was corrected for F.R. in a series of solvents and solvent systems, and unperturbed vC=O was correlated with mole % solvent A/solvent B, and other parameters. The cause of shifts of vC=O in solvent systems is the result of several parameters, including bulk dielectric effects, basicity of the carbonyl group, and steric factors of both the solute and solvent.", pages = "791-796", url = "http://www.ingentaconnect.com/content/sas/sas/1990/00000044/00000005/art00005", doi = "doi:10.1366/0003702904087055", keyword = "Infrared, Solvent effects, Fermi resonance, Carbonyl stretching frequency" }