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Infrared Spectra of Tetramethylammonium Halides

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Abstract:

Infrared spectra of tetramethylammonium (TMA) halides are discussed with an emphasis on perturbations of the hydrogen vibrational motions caused by anion effects in aqueous solution. The fully deuterated molecule is included in the discussion. The effect of halide anion concentration on the C-H stretching region of the IR spectrum is presented. It is concluded that hydrogen bonding is not the cause of the shift of the wavenumber of these modes.

Keywords: Concentration effects on vC-H; Infrared; Solution infrared spectra; Tetramethylammonium ions

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702904087244

Affiliations: The Dow Chemical Company, Analytical Research Group, 463 Building, P.O. Box 1398, Pittsburg, California 94565

Publication date: May 1, 1990

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sas/sas/1990/00000044/00000004/art00023
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