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Ionization of Organic Molecules Using Coherent Vacuum Ultraviolet Light

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Abstract:

Third harmonic generation in xenon was used to produce vacuum ultraviolet light at a fixed wavelength of 118 nm. These photons were able to ionize a number of organic molecules with negligible yields of fragmentation ions. This method yielded far simpler mass spectra than those utilizing electron impact ionization. Absolute photoionization cross sections were measured for six organic compounds at 118.2 nm.

Keywords: Ionization; Molecules; Ultraviolet

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702894203633

Affiliations: Chemical Physics Section, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6378

Publication date: September 1, 1989

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