If you are experiencing problems downloading PDF or HTML fulltext, our helpdesk recommend clearing your browser cache and trying again. If you need help in clearing your cache, please click here . Still need help? Email help@ingentaconnect.com

Matrix Effects in Matrix Isolation Infrared Spectroscopy

$29.00 plus tax (Refund Policy)

Buy Article:


A major factor limiting extensive use of matrix isolation gas chromatography-Fourier transform infrared spectrometry is the incompatibility of matrix-isolated spectra with available vapor-or condensed-phase spectral data bases. Here, matrix and surface effects on matrix isolation infrared spectra of organic molecules are investigated. Use of xenon at −215°C (58 K) to obtain matrix isolation spectra that are similar to condensed-phase spectra is demonstrated. Finally, the effect of temperature on reflection-absorption infrared spectra of matrix-isolated molecules is discussed, and guidelines for obtaining and interpreting matrix isolation infrared spectra of gas chromatographic eluants using the existing condensed phase data bases are provided.

Keywords: Infrared; Instrumentation, matrix isolation GC-IR

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702894202274

Affiliations: Department of Chemistry, University of California, Riverside, California 92521

Publication date: July 1, 1989

More about this publication?
Related content



Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more