Considerations on the Simultaneous Behavior of the Resonance Fluorescence and Ionization Signals Versus Laser Intensity in Flames

Authors: Omenetto, N.¹; Smith, B.W.²; Jones, B.T.²; Winefordner, J.D.²

Source: Applied Spectroscopy, Volume 43, Issue 4, Pages 595-729 (May/June 1989) , pp. 595-598(4)

Publisher: Society for Applied Spectroscopy

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Abstract:

By the use of a rate equation approach and a disregard for recombination between ions and electrons, the variation of fluorescence and ionization signals as a function of laser intensity is given. Plots of ion and photon yields vs. laser intensity for various values of important parameters are given and are discussed with respect to the significance of collisional ionization and photoionization.

Keywords: Laser-enhanced ionization

Document Type: Rapid communication

DOI: http://dx.doi.org/10.1366/0003702894202391

Affiliations: 1: Department of Chemistry, University of Florida, Gainesville, Florida 32611; permanent address: Joint Research Center, Environment Institute, 21020 Ispra, Varese, Italy 2: Department of Chemistry, University of Florida, Gainesville, Florida 32611

Publication date: 1989-05-01

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