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Atomization of Organic Compounds in the Inductively Coupled Plasma

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Abstract:

The problem of incomplete atomization when nonmetals are being determined in aspirated organic solutions was studied. Abel inverted spatial profiles of C2, CN, C(I) and S(I) emission were acquired at several heights. It was found that molecular emission caused by the analyte is restricted to the lower aerosol channel. Nonmetal atomic emission is found in the toroidal region and higher up in the aerosol channel. Compounds that contained nonmetals comprised of either oxygen, nitrogen, or sulfur, which were dissolved in xylene, exhibited nonmetal emission intensities independent of the structure of the compound.

Keywords: Analysis for oxygen, nitrogen, and sulfur; Emission spectroscopy; Photodiode array

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702884429373

Affiliations: 1: Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Y6, Canada; current address: Department of Chemistry, LaTrobe University, Bundoora, Victoria, 3083 Australia 2: Department of Chemistry, University of British Columbia, Vancouver, British Columbia V6T 1Y6, Canada

Publication date: May 1, 1988

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