Vibrational Spectra of Some Cyclic Polysulfides

Authors: Nash, Charles P.; Musker, W. Kenneth; Lam, Ada P.J.

Source: Applied Spectroscopy, Volume 42, Issue 3, Pages 381-529 (March/April 1988) , pp. 494-497(4)

Publisher: Society for Applied Spectroscopy

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Abstract:

Vibrational spectra and normal-coordinate analyses using a modified Urey-Bradley force field are reported for 1,2,3,5,6-pentathiepane (lenthionine), 1,3,5,7-tetrathiocane, and 1,2,3-trithiane. Characteristic Raman bands are identified for S-CH₂-S and S-S-S functionalities in cyclic molecules.

Keywords: Vibrational spectra; Force constants; Cyclic polysulfides

Document Type: Research article

DOI: http://dx.doi.org/10.1366/0003702884428004

Affiliations: 1: Department of Chemistry, University of California, Davis, California 95616

Publication date: 1988-03-01

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