Investigation of the Effect of Gamma-Radiation on High-Density Polyethylene by Solid-State Magic-Angle 13C NMR Spectroscopy

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Abstract:

The structural and morphological changes occurring in high-density polyethylene when exposed to gamma-radiation have been investigated by high-resolution solid state 13C NMR, NMR measurements are used to study the effect of gamma-radiation on crystalline and amorphous components. In addition, resonance peaks due to direct cross-links have been detected. The changes in main chain unsaturation are also studied.

Keywords: Molecular structure; NMR

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702874447158

Affiliations: 1: Macromolecular Science Department, Case Western Reserve University, Cleveland, Ohio 44106; present address: The BOC Group, Inc., Murray Hill, NJ 07974 2: Macromolecular Science Department, Case Western Reserve University, Cleveland, Ohio 44106

Publication date: November 1, 1987

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