Vibrational Circular Dichroism Measurement in the Frequency Range of 800 to 650 cm−1

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Abstract:

The development of dispersive instrumentation for the measurement of vibrational circular dichroism (VCD) with a lower frequency limit of ∼650 cm−1 is reported. VCD spectra of 3-methylcyclohexanone, α-pinene, and 3-bromocamphor in the frequency range of 800 to 650 cm−1 are presented to illustrate instrumental performance. The spectra obtained are superior to earlier spectra obtained with the use of a Fourier transform spectrometer.

Keywords: Infrared; Spectroscopic techniques; Vibrational circular dichroism

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702874447581

Affiliations: Department of Chemistry, University of Southern California, Los Angeles, California 90089-0482

Publication date: September 1, 1987

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