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Vibrational Analysis of Terephthalate and Terephthalate-d4 Ions

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Abstract:

Infrared and Raman spectra of the terephthalate and terephthalate-d4, ions have been obtained. Normal coordinate analysis was carried out for both ions by transferring force fields from previous work on aromatic esters and p-nitro-benzoate and then refining all the force constants for the carboxylate groups and the diagonal force constants for the benzene rings by a first-order perturbation technique. An interpretation of the observed spectra has been proposed and selected eigenvectors have been presented.

Keywords: Infrared; Raman spectroscopy; Vibrational analysis

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702874448968

Affiliations: Department of Materials Science and Engineering, University of Cincinnati, Cincinnati, Ohio 45221

Publication date: March 1, 1987

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