Feasibility of Quantitative UV Resonance Raman Spectroscopy with a KrF Excimer Laser

$29.00 plus tax (Refund Policy)

Buy Article:


The feasibility of quantitative resonance Raman spectroscopy with a KrF excimer laser providing primary radiation at 249 nm has been examined. The instrumentation is described, and results are reported for measurements with a photomultiplier detector and scanning monochromator. Considerations affecting the success of the internal standardization are described. A least-squares fitting procedure is employed for quantifying the overlapped analyte and internal standard spectral lines. Instrumental detection limits of 2.2, 1.2, and 1.0 mg/L are reported for anthracene, 9-methylanthracene, and 2-methylanthracene, respectively, for spectra obtained with 120 laser pulses per step. Detection limits in the low ppb range are projected for a system employing an intensified diode array detector.

Keywords: Anthracene; Excimer laser; Raman; UV resonance

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702874449002

Affiliations: Department of Chemistry, Florida State University, Tallahassee, Florida 32306-3006

Publication date: March 1, 1987

More about this publication?
Related content



Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more