Correlation of Adsorption/Desorption Processes on Pigment Surfaces

Author: McKenzie, Martin T.

Source: Applied Spectroscopy, Volume 41, Issue 1, Pages 1-165 (January 1987) , pp. 111-116(6)

Publisher: Society for Applied Spectroscopy

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Abstract:

An approach utilizing diffuse reflectance FT-IR is described whereby the desorption of carbon monoxide from a pigment surface is correlated with the adsorption of two organo-functional silane materials, 3-chloropropylsilane (CPS) and 3-methacryloxypropyltrimethoxysilane (MPS). Correlation of observables from a single set of measurements provides an efficient means to determine the results of adsorption as a function of adsorbate structure and treatment solution concentration.

Keywords: CPS adsorption, MPS adsorption; Diffuse reflectance FT-IR; Surface analysis

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702874868115

Affiliations: Automotive Products Division, E.I. DuPont de Nemours and Co., Inc., Marshall Laboratory, Philadelphia, Pennsylvania 19146

Publication date: January 1, 1987

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