Novel High-Pressure FT-IR Spectroscopic System Combined with Specially Designed In Situ IR Cell for Studying Heterogeneous Catalytic Reactions

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Abstract:

In situ spectroscopy has become increasingly important for the research of catalytic reactions over solid catalysts because of the valuable information it provides for the elucidation of the reaction mechanism under actual industrial conditions. In particular, in situ IR spectroscopy is very useful for the observation of surface species, such as adsorbed reactants, possible intermediates, and products associated with the catalytic surface reaction that have formed on the catalyst. A typical industrial process is that which involves surface reactions which are the syntheses of methanol and ammonia.

Keywords: Analytical methods; Infrared; Spectroscopic techniques

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702864508449

Affiliations: 1: National Chemical Laboratory for Industry, Yatabe, Ibaraki, 305, Japan 2: Sagami Chemical Research Center, 4-4-1 Nishi-Onuma, Sagamihara, Kanagawa, 510, Japan; present address: Department of Chemical Process Engineering, Faculty of Engineering, Yokohama National University, 156 Tokiwadai, Hodogaya-ku, Yokohama 240, Japan 3: Sagami Chemical Research Center, 4-4-1 Nishi-Onuma, Sagamihara, Kanagawa, 510, Japan; present address: Research Institute for Catalysis, Hokkaido University, Sapporo 060, Japan

Publication date: August 1, 1986

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