A Multisurface Matrix-Isolation Apparatus

Authors: Hauge, Robert H.; Fredin, Leif; Kafafi, Zakya H.; Margrave, John L.

Source: Applied Spectroscopy, Volume 40, Issue 5, Pages 583-716 (July 1986) , pp. 588-595(8)

Publisher: Society for Applied Spectroscopy

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Abstract:

A multisurface matrix-isolation apparatus has been designed and interfaced to an FT-IR vacuum spectrometer. The design permits independent matrix-isolation studies with sixty different surfaces. It also allows direct measurement of matrix gas to guest ratios with an integral cooled quartz crystal microbalance. Problems associated with moving the matrix block while maintaining good thermal contact are discussed. Finally, some applications to studies of coal pyrolysis, metal atom chemistry, and quantitative analysis are presented.

Keywords: Analysis, for coal; Infrared; Instrumentation, emission spectroscopy; Instrumentation, matrix isolation; Analytical methods

Document Type: Research article

DOI: http://dx.doi.org/10.1366/0003702864508601

Affiliations: 1: Department of Chemistry and Rice Quantum Institute, Rice University, Houston, Texas 77251

Publication date: 1986-07-01

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