A Constant-Temperature Raman Cell for the Study of Supersaturated Aqueous Solutions

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Abstract:

In order that the phenomena of crystal nucleation and growth from solution can be fully understood, the current knowledge of supersaturated solution structure must be extended. Previous studies on Raman spectroscopy of aqueous metal nitrate solutions indicated the presence of solvated ions, solvent separated ion pairs, contact ion pairs, and ion agglomerates as a function of concentration. Unfortunately, the concentration range of these studies did not include supersaturated solutions. It is the purpose of this work to describe an experimental technique which allows the study of supersaturated solutions.

Keywords: Raman spectroscopy; Solution Raman spectra; Spectroscopic techniques

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702864509466

Affiliations: 1: Department of Chemical Engineering, Iowa State University, Ames, Iowa 50011 2: Departments of Agricultural and Chemical Engineering, Michigan State University, East Lansing, Michigan 48824

Publication date: February 1, 1986

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