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Concentration Profiling in Layered Liquids Using a Laser Photoacoustic Probe

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Abstract:

An aluminum-coated Pyrex┬« glass rod is used both as a photoacoustic probe and as a laser light guide to examine a three-layer solution of carbon tetrachloride, hexane, and an aqueous solution of an efficient chromophore, ferroin. The boundaries of the layers show up clearly on a signal amplitude vs. penetration depth graph. A Beer's law plot of the ferroin solution alone shows that the probe is capable of analytical determinations down to 10−7 M. Reflections from the cell walls may cause interference in quantitative analysis if the size of the cell is too small. The sensitivity of the probe is compared with that of a typical photo-acoustic cell, and it is found that the probe only attenuates the signal amplitude by ~35%. Finally, it is found that the signal amplitude transmitted by the photoacoustic probe is roughly proportional to its diameter.

Keywords: Analytical methods; Instrumentation, photoacoustic spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702864509439

Affiliations: Carleton University, Department of Chemistry, Ottawa, Ontario K1S 5B6, Canada

Publication date: February 1, 1986

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