Far-IR Studies of Carbon Acid Complexes of 18-Crown-6

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Bands in the far-IR spectra of 18-crown-6 complexes of nitromethane, acetronitrile, and malonodinitrile are attributed to hydrogen bonding. The v σ vibrational mode is assigned for these neutral complexes. Solution studies of the complexes in CHCl3 show that a substantial amount of both the nitromethane complex and the malonodinitrile complex remains intact. The acetonitrile complex, however, appears to dissociate in CHCl3.

Keywords: Far-infrared spectroscopy; Neutral crown ether complexes

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702864815600

Affiliations: Department of Chemistry, University of Utah, Salt Lake City, Utah 84112

Publication date: January 1, 1986

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