High-Resolution Infrared Spectroscopy Using a Temperature-Controlled Long-Path Absorption Cell: The v 3 Band of Uranium Hexafluoride at 16 μm

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High-resolution UF6 absorption spectra at 16 μm have been obtained with the use of tunable diode lasers and a long-pathlength (~103-m) sample cell. The frequencies of the v 3 Q-branch subband heads for both 238UF6 and 235UF6 have been determined, along with those for the (v 3 + v 6) − v 6 "hot-band" transition. Band contour studies have been carried out as a function of temperature, and comparisons are made with previous work.

Keywords: Infrared; Lasers, semiconductors; Molecular structure; Spectroscopic techniques

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702854249745

Affiliations: Los Alamos National Laboratory, Los Alamos, New Mexico 87545

Publication date: November 1, 1985

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