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Polarized FT-IR Spectra of Benzene and Anthracene Oriented in a Nematic Liquid Crystal Solvent

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Abstract:

Polarized FT-IR spectra have been obtained for benzene and anthracene oriented in a nematic liquid crystal solvent (Merck 1132) and allow vibrational symmetry assignments to be proposed for those fundamentals detected in the mid-IR region of the dichroic spectra. The symmetry assignments proposed for anthracene are in excellent agreement with those from earlier, technically more difficult, single-crystal IR transmission measurements.

Keywords: Infrared; Spectroscopic techniques

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702854250112

Affiliations: Department of Chemistry, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 2K6, Canada

Publication date: July 1, 1985

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