The Infrared Spectra and Structure of the Amadori Product Formed from Glucose and Glycine

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Abstract:

IR spectra are given for 1-deoxy-1-glycino-D-fructose as an anion, cation, zwitterion, and deuterated zwitterion. The major bands are assigned to the vibrations of molecular subgroups. The spectra show that the deoxyfructose residue is predominately in the β-D-pyranose form, although small fractions of other isomers may also be present. These results may be useful in the study of nonenzymatically glycosylated proteins.

Keywords: Analyses for anomeric forms; Infrared; Molecular structure

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702854250095

Affiliations: 1: Department of Biochemistry and Biophysics, University of Rhode Island, Kingston, Rhode Island 02881; present address: University of Southern California, Cancer Research Lab, Room 106, 1303 N. Mission Road, Los Angeles, CA 90033 2: Department of Biochemistry and Biophysics, University of Rhode Island, Kingston, Rhode Island 02881

Publication date: July 1, 1985

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