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Coherent Anti-Stokes Raman Spectroscopy of Commercial Oil Samples

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Abstract:

Three commercial oil samples were analyzed with the use of the selectivity of resonance CARS. No fractionation procedures were used; the oil samples were simply dissolved in an appropriate solvent and pumped from 365 nm to 480 nm. All three samples could be differentiated by characteristic Raman bands at various pump wavelengths. In addition, comparisons between the CARS spectra of the oil samples and the CARS spectra of pure PAHs at the same pump wavelength yielded tentative identifications of perylene and benzo(ghi)perylene in two of the samples.

Keywords: Instrumentation, CARS; Raman spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702854248890

Affiliations: 1: University of Georgia, Department of Chemistry, Athens, Georgia 30602; present address: Savannah River Laboratory, E. I. DuPont de Nemours and Co., Inc., Aiken, SC 29801 2: University of Georgia, Department of Chemistry, Athens, Georgia 30602

Publication date: March 1, 1985

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