Technique for Measuring the Amount of Pressure-induced Polarization Scrambling by Optical Windows in High Pressure Light Scattering Cells

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Abstract:

A simple method for estimating the amount of pressure-induced polarization scrambling by optical windows in the high pressure Raman scattering cells is proposed. This method is based on the measurement of the depolarization ratio ρ for a polarized band (ρ = 0) for which a nonzero value of ρ is produced by the leakage of the I vv component due to stress-induced birefringence of the window material. As an illustrative example the measurement of ρ for the polarized ν3(A1) band in liquid tetramethyltin is presented.

Keywords: High pressure; Optical windows; Polarization scrambling

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702834634334

Affiliations: 1: Department of Chemistry, School of Chemical Sciences, University of Illinois, 1209 W. California, Urbana, Illinois 61801; present address: NCA Corporation, Sunnyvale, CA 94086 2: Department of Chemistry, School of Chemical Sciences, University of Illinois, 1209 W. California, Urbana, Illinois 61801; present address: Union Camp R & D Labs, Princeton, NJ 08690 3: Department of Chemistry, School of Chemical Sciences, University of Illinois, 1209 W. California, Urbana, Illinois 61801

Publication date: July 1, 1983

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