Fourier Transform Infrared Analysis of the Ammoxidation of 4-Methylthiazole over a Metal Oxide Catalyst

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Abstract:

The gaseous products of the reaction of 4-methylthiazole (4-MT), air, 14NH3, and 15NH3 have been analyzed by on-line Fourier transform infrared spectroscopy. The products observed, including those due to partial and full oxidation, account for 95 to 98% of the starting 4-MT. Estimates of the activation energy (20 kcal/mol) and the excess heat due to combustion (350 kcal/mol/ mol of 4-MT combusted) have been calculated. In addition, we have observed an unexpected reaction that is formally bimolecular in 4-MT.

Keywords: Analysis, for ammoxidation of 4-methylthiazole; Infrared

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702834634596

Affiliations: Merck Sharp and Dohme Research Laboratories, P.O. Box 2000, Rahway, New Jersey 07065; current address: IBM Instruments, Inc., 40 West Brokaw Rd., San Jose, CA 95110

Publication date: May 1, 1983

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