Librational Modes of Water in Zinc Formate Dihydrate

$29.00 plus tax (Refund Policy)

Buy Article:

Abstract:

The infrared spectra of zinc formate dihydrate are presented for the region 1000 to 400 cm−1 along with the laser-excited Raman spectra. With the use of the corresponding IR and Raman spectra for the deuterated and anhydrous samples and their temperature dependence (between 300 to 90 K), two sets of bands for the in-plane bending mode of formate ion and all the three librations of water have been identified corresponding to two types of formate and water in the unit cell. The large shift of the formate v 3 mode in going from the hydrate to the deuterate has been attributed to a dynamic interaction of this mode with the close-lying H2O rocking mode.

Keywords: Infrared; Molecular structure; Raman spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702824639556

Affiliations: 1: Department of Physics, H. B. Technological Institute, Kanpur 208016, India 2: Indian Institute of Technology, Kanpur 208016, India

Publication date: July 1, 1982

More about this publication?
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more