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Vibrational Spectra and Normal Coordinate Calculations of Chlorophosphazene Compounds. III. Polydichlorophosphazene

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Abstract:

Vibrational spectra and normal coordinate calculations of polydichlorophosphazene (PDP) are presented. The valence force field derived previously from the two conformers of octachlorocyclotetraphosphazene was directly transferred to a distorted "cis-plan" helical model of PDP without refinement. A reasonable agreement between the observed and calculated frequencies was obtained and the assignment of the normal modes of PDP is discussed.

Keywords: Infrared; Normal coordinate analysis; Raman spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702824638629

Affiliations: Material Science and Engineering Department, Polymer Science Section, The Pennsylvania State University, University Park, Pennsylvania 16802

Publication date: May 1, 1982

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