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Vibrational Spectra and Normal Coordinate Calculations of Chlorophosphazene Compounds. II. Octachlorocyclotetraphosphazene

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Abstract:

Vibrational spectra and normal coordinate calculations of octachlorocyclotetraphosphazene (OCTP) are presented. A common valence force field for the two conformers (T and K forms) of OCTP has been developed. A good agreement between the observed and calculated frequencies of OCTP was obtained and the assignments of the normal modes are discussed.

Keywords: Infrared; Normal coordinate analysis; Raman spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702824638656

Affiliations: Polymer Science Section, Materials Science and Engineering Department, The Pennsylvania State University, University Park, Pennsylvania 16802

Publication date: May 1, 1982

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