Vibrational Spectra and Normal Coordinate Calculations of Chlorophosphazene Compounds. I. Hexachlorocyclotriphosphazene

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Abstract:

Vibrational spectra and normal coordinate calculations of hexachlorocyclotriphosphazene (HCTP) are presented. Attempts to obtain a common valence force field for HCTP and the two conformers of octachlorocyclotetraphosphazene which were not successful, are discussed. The force field obtained for HCTP is, by necessity, relatively simple. Nevertheless, we have been able to make assignments of the normal modes and resolve some apparent discrepancies in the literature.

Keywords: Infrared; Normal coordinate analysis; Raman spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702824638548

Affiliations: Polymer Science Section, Materials Science and Engineering Department, The Pennsylvania State University, University Park, Pennsylvania 16802

Publication date: May 1, 1982

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