Thermal Lensing Colorimetry of Nitrite Ion with Single-laser System

Authors: Fujiwara, Kitao1; Uchiki, Hisao2; Shimokoshi, Fumio2; Tsunoda, Kin-Ichi1; Fuwa, Keiichiro1; Kobayashi, Takayoshi2

Source: Applied Spectroscopy, Volume 36, Issue 2, Pages 87-189 (March/April 1982) , pp. 157-161(5)

Publisher: Society for Applied Spectroscopy

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Abstract:

Thermal lensing colorimetry has been applied to the determination of nitrite ion. Color development was based on the diazo-coupling reaction among NO2 , N-(naphthyl)-ethylenediamine dihydrochloride, and sulfanylamide. The source was the chopped output of an Ar+ laser operated at 514.5 nm. The beam intensity was measured with a silicon photocell of 1 mm2 surface area and the resultant electrical signal was processed with a microcomputer system. The minimal detectable amount of nitrite ion using a cell of 1 cm path length is 0.2 nM. This is more than 200 times smaller than the detection limit of ordinary spectrophotometry using a commercial spectrophotometer.

Keywords: Analysis, nitrate ion; Lasers, cw Ar+; Visible, UV spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702824638836

Affiliations: 1: Department of Chemistry, University of Tokyo, Bunkyo-ku, Tokyo 113, Japan 2: Department of Physics, University of Tokyo, Bunkyo-ku, Tokyo 113, Japan

Publication date: March 1, 1982

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